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Journal Articles

Radiochemical research for the advancement of $$^{99}$$Mo/$$^{rm 99m}$$Tc generator by (n, $$gamma$$) method, 3

Fujita, Yoshitaka; Seki, Misaki; Namekawa, Yoji*; Nishikata, Kaori; Daigo, Fumihisa; Ide, Hiroshi; Tsuchiya, Kunihiko; Sano, Tadafumi*; Fujihara, Yasuyuki*; Hori, Junichi*; et al.

KURNS Progress Report 2020, P. 136, 2021/08

no abstracts in English

Journal Articles

Online solid-phase extraction-inductively coupled plasma-quadrupole mass spectrometry with oxygen dynamic reaction for quantification of technetium-99

Matsueda, Makoto; Yanagisawa, Kayo*; Koarai, Kazuma; Terashima, Motoki; Fujiwara, Kenso; Abe, Hironobu; Kitamura, Akihiro; Takagai, Yoshitaka*

ACS Omega (Internet), 6(29), p.19281 - 19290, 2021/07

 Times Cited Count:2 Percentile:14.88(Chemistry, Multidisciplinary)

Online solid-phase extraction-inductively coupled plasma-quadrupole mass spectrometry with oxygen dynamic reaction cell (online SPE-ICP-MS-DRC) was shown to be a thorough automatic analytical system, circumventing the need for human handling. At three stepwise separations (SPE-DRC-Q mass filters), we showed that interference materials allowed the coexistence of abundance ratios of 1.5$$times$$10$$^{-13}$$ for $$^{99}$$Tc/Mo. Using this optimized system, a detection limit of $$^{99}$$Tc was 9.3 pg/L (5.9 mBq/L) for a 50 mL injection and sequential measurements were undertaken at a cycle of 24 min/sample.

Journal Articles

Production of $$^{9}$$$$^{9}$$Mo and its application in neclear medicine

;

Journal of Radioanalytical and Nuclear Chemistry, 102(2), p.533 - 550, 1986/02

 Times Cited Count:8 Percentile:66.77(Chemistry, Analytical)

no abstracts in English

Journal Articles

Determination of Small Amounts of Tc-99 in Fission Products

Ueno, Kaoru

Nihon Kagaku Zasshi, 90(7), p.718 - 719, 1969/00

no abstracts in English

Oral presentation

Online solid-phase extraction ICP-MS for determination of technetium-99 in environmental samples

Matsueda, Makoto; Terashima, Motoki; Takagai, Yoshitaka*

no journal, , 

Technetium-99 ($$^{99}$$Tc) is a pure beta-emitting radionuclide with a long half-life (210 000 years), produced with a yield of about 6% during the fission of $$^{235}$$U and $$^{239}$$Pu. The properties of high mobility in environment and concentrated into specific seaweeds were applied as a tracer for radioisotopes released into the environment. Inductively coupled plasma-mass spectrometry (ICP-MS) is the main method for $$^{99}$$Tc analysis; however, the isobars ($$^{99}$$Ru and $$^{98}$$MoH) interfere the quantification. In this study, a multi-stage separation and analysis system (online SPE-ICP-MS) for $$^{99}$$Tc was constructed by attaching a solid phase extraction (SPE) resin to a flow injection (FI) system and combining it with a collision reaction cell (CRC) in an ICP-MS. In addition, a high sensitivity for detecting trace amounts of $$^{99}$$Tc was developed.

Oral presentation

Development of rapid and easy analytical method for difficult-to-measure radionuclides

Matsueda, Makoto

no journal, , 

no abstracts in English

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